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Experimental investigation of evolutive mode-I and mode-II fracture behavior of fiber-reinforced cemented

《结构与土木工程前沿（英文）》 2023年 第17卷 第2期   页码 256-270 doi: 10.1007/s11709-022-0924-z

摘要： The curing temperature-dependent cement hydration causes the nonlinear evolution of fracture behavior and properties of fiber-reinforced cemented paste backfill (CPB) and thus influences the stability of mine backfill materials in deep mines. Therefore, the coupled effect of curing temperature (20, 35, and 45 °C) and cement hydration at different curing times (3, 7, and 28 d) on the mode-I and mode-II fracture behavior and properties of fiber-reinforced CPB is investigated. A comprehensive experimental testing program consisting of semicircular bend tests, direct shear tests, measurement of volumetric water content and matric suction, TG/DTG tests, and SEM observation is carried out. The results show that the coupled thermochemical effect results in strongly nonlinear development of pre- and post-peak behavior of fiber-reinforced CPB. Moreover, the results discover a positive linear correlation between fracture toughness and shear strength parameters and also reveal the vital role played by matric suction in the formation of fracture toughness. Furthermore, predictive functions are developed to estimate the coupled thermochemical effect on the development of KIc and KIIc. Therefore, the findings and the developed mathematical tools have the potential to promote the successful application of fiber-reinforced CPB technology in deep underground mines.

关键词： fiber reinforcement     cemented paste backfill     fracture behavior     underground mine     cement hydration    

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Effects of delamination in drilling glass/polyester composite

Mehdi GANJIANI, Majid SAFARABADI, Nabi MEHRI-KHANSARI, Hossein ORUJI

《结构与土木工程前沿（英文）》 2021年 第15卷 第2期   页码 552-567 doi: 10.1007/s11709-021-0699-7

摘要： Considering failures during machinery processes such as drilling, a precautionary analysis involving delamination and the corresponding dissipated energy is required, especially for composite structures. In this context, because of the complexity of both the analysis procedure and experimental test setup, most studies prefer to represent mode I and III interlaminar crack propagation instead of that involving mode II. Therefore, in this study, the effect of mode delamination and corresponding interlaminar crack propagation was considered during the drilling process of multilayered glass/polyester composites using both numerical and experimental approaches. In the experimental procedure, the mechanical properties of the glass/polyester specimens were obtained according to ASTM D3039. In addition, the interlaminar mixed-mode (I/II) loadings were determined using an ARCAN test fixture so that the fracture toughness of glass/polyester could then be identified. The mode II critical strain energy release rate (CSERR) was then obtained using an experimental test performed using an ARCAN fixture and the virtual crack closure technique (VCCT). It was determined that the numerical approach was in accordance with the experiments, and more than 95% of crack propagation could be attributed to mode II compared to the two other modes.

关键词： delamination     VCCT     ARCAN specimen     drilling     mode II    

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electrolysis cells with biocathodes and driven by microbial fuel cells for simultaneous enhanced Co(II) and Cu(II) removal

Jingya SHEN,Yuliang SUN,Liping HUANG,Jinhui YANG

《环境科学与工程前沿（英文）》 2015年 第9卷 第6期   页码 1084-1095 doi: 10.1007/s11783-015-0805-y

摘要： Cobalt and copper recovery from aqueous Co(II) and Cu(II) is one critical step for cobalt and copper wastewaters treatment. Previous tests have primarily examined Cu(II) and Co(II) removal in microbial electrolysis cells (MECs) with abiotic cathodes and driven by microbial fuel cell (MFCs). However, Cu(II) and Co(II) removal rates were still slow. Here we report MECs with biocathodes and driven by MFCs where enhanced removal rates of 6.0±0.2 mg?L ?h for Cu(II) at an initial concentration of 50 mg?L and 5.3±0.4 mg?L h for Co(II) at an initial 40 mg?L were achieved, 1.7 times and 3.3 times as high as those in MECs with abiotic cathodes and driven by MFCs. Species of Cu(II) was reduced to pure copper on the cathodes of MFCs whereas Co(II) was removed associated with microorganisms on the cathodes of the connected MECs. Higher Cu(II) concentrations and smaller working volumes in the cathode chambers of MFCs further improved removal rates of Cu(II) (115.7 mg?L ?h ) and Co(II) (6.4 mg?L ?h ) with concomitantly achieving hydrogen generation (0.05±0.00 mol?mol COD). Phylogenetic analysis on the biocathodes indicates dominantly accounted for 67.9% of the total reads, followed by (14.0%), (6.1%), (2.5%), (1.4%), and (1.0%). This study provides a beneficial attempt to achieve simultaneous enhanced Cu(II) and Co(II) removal, and efficient Cu(II) and Co(II) wastewaters treatment without any external energy consumption.

关键词： biocathode     microbial electrolysis cell     microbial fuel cell     Cu(II) removal     Co(II) removal    

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anti-seismic engineering measures for intake tower based on non-dominated sorting genetic algorithm-II

《结构与土木工程前沿（英文）》   页码 1428-1441 doi: 10.1007/s11709-023-0998-2

摘要： High-rise intake towers in high-intensity seismic areas are prone to structural safety problems under vibration. Therefore, effective and low-cost anti-seismic engineering measures must be designed for protection. An intake tower in northwest China was considered the research object, and its natural vibration characteristics and dynamic response were first analyzed using the mode decomposition response spectrum method based on a three-dimensional finite element model. The non-dominated sorting genetic algorithm-II (NSGA-II) was adopted to optimize the anti-seismic scheme combination by comprehensively considering the dynamic tower response and variable project cost. Finally, the rationality of the original intake tower antiseismic design scheme was evaluated according to the obtained optimal solution set, and recommendations for improvement were proposed. The method adopted in this study may provide significant references for designing anti-seismic measures for high-rise structures such as intake towers located in high-intensity earthquake areas.

关键词： intake tower     NSGA-II     mode decomposition response spectrum method     anti-seismic engineering measures     optimization design     variable project cost    

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A microextraction approach for rapid extraction and separation of Mn(II) and Co(II) using saponified

《化学科学与工程前沿（英文）》 2022年 第16卷 第6期   页码 963-972 doi: 10.1007/s11705-021-2081-7

摘要： In this paper, we proposed a microextraction approach for the extraction and separation of Mn(II) and Co(II) from sulfate solution simulating leachate of spent lithium-ion battery cathode materials using saponified di-(2-ethylhexyl)phosphoric acid system. The effects of the following operational variables were investigated: equilibrium pH, tri-n-butyl phosphate concentration, saponification rate, two-phase ratio and residence time. The results showcased that the microextractor can reach the extraction equilibrium within 20 s, thereby greatly reducing necessary extraction time comparing to that of conventional processes. The volumetric mass transfer coefficient showed 8–21 times larger than that of batch device. With the help of microextractor, 95% of Mn(II) was extracted with a single theoretical stage at a chosen two-phase ratio of 3:1, and the separation factor βMn/Co was as large as 65.5. In the subsequent stripping step, more than 99% of manganese from loaded phase was easily stripped under optimal conditions. The microextraction approach greatly enhances the mass transfer while enabling a continuous and controllable extraction process within a simple structure design. When extracting spent electrode material with microextractors, the comprehensive recovery of mangenese can reach 96%. The microextraction approach has a good applicability in the spent lithium-ion battery cathode materials recycling at both bench and industrial scales.

关键词： extraction equilibrium     mass transfer coefficient     microextraction     multicomponent extraction     di-(2-ethylhexyl)phosphoric acid    

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Co-present Pb(II) accelerates the oxidation of organic contaminants by permanganate: Role of Pb(III)

《环境科学与工程前沿（英文）》 2022年 第16卷 第8期 doi: 10.1007/s11783-022-1530-y

摘要：

• Simultaneous removal of organic contaminants and Pb(II) was achieved by Mn(VII).

关键词： Permanganate     Pb(II) oxidation     MnO2     pH effect    

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Approaching the binding between Cu(II) and aerobic granules by a modified titration and µ-XRF

Hongwei LUO,Longfei WANG,Zhonghua TONG,Hanqing YU,Guoping SHENG

《环境科学与工程前沿（英文）》 2016年 第10卷 第2期   页码 362-367 doi: 10.1007/s11783-015-0803-0

摘要： Interactions between metals and activated sludge can substantially affect the fate and transport of heavy metals in wastewater treatment plants. Therefore, it is important to develop a simple, fast and efficient method to elucidate the interaction. In this study, a modified titration method with a dynamic mode was developed to investigate the binding of Cu(II), a typical heavy metal, onto aerobic granules. The titration results indicated that pH and ionic strength both had a positive effect on the biosorption capacity of the granular sludge. The -XRF results demonstrated that the distribution of metals on the granular surface was heterogeneous, and Cu showed strong correlations and had the same “hot spots” positions with other metal ions (e.g., Ca, Mg, Fe etc.). Ion exchange and complexing were the main mechanisms for the biosorption of Cu(II) by aerobic granules. These results would be beneficial for better understanding of Cu(II) migration and its fate in wastewater treatment plants.

关键词： aerobic granules     Cu(II)     modified titration     µ-XRF analysis    

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Multi-objective optimization of a hybrid distributed energy system using NSGA-II algorithm

Hongbo REN, Yinlong LU, Qiong WU, Xiu YANG, Aolin ZHOU

《能源前沿（英文）》 2018年 第12卷 第4期   页码 518-528 doi: 10.1007/s11708-018-0594-7

摘要：

In this paper, a multi-objective optimization model is established for the investment plan and operation management of a hybrid distributed energy system. Considering both economic and environmental benefits, the overall annual cost and emissions of CO2 equivalents are selected as the objective functions to be minimized. In addition, relevant constraints are included to guarantee that the optimized system is reliable to satisfy the energy demands. To solve the optimization model, the non-dominated sorting generic algorithm II (NSGA-II) is employed to derive a set of non-dominated Pareto solutions. The diversity of Pareto solutions is conserved by a crowding distance operator, and the best compromised Pareto solution is determined based on the fuzzy set theory. As an illustrative example, a hotel building is selected for study to verify the effectiveness of the optimization model and the solving algorithm. The results obtained from the numerical study indicate that the NSGA-II results in more diversified Pareto solutions and the fuzzy set theory picks out a better combination of device capacities with reasonable operating strategies.

关键词： multi-objective optimization     hybrid distributed energy system     non-dominated sorting generic algorithm II     fuzzy set theory     Pareto optimal solution    

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Removal of Ni(II) ions from wastewater by micellar enhanced ultrafiltration using mixed surfactants

Amar D. Vibhandik, Kumudini V. Marathe

《化学科学与工程前沿（英文）》 2014年 第8卷 第1期   页码 79-86 doi: 10.1007/s11705-014-1407-0

摘要： Ni(II) ions were removed from aqueous waste using micellar enhanced ultrafiltration (MEUF) with a mixture of surfactants. The surfactant mixture was the nonionic surfactant Tween 80 (TW80) mixed with the anionic surfactant sodium dodecyl sulfate (SDS) in different molar ratios ranging from 0.1–1.5. The operational variables of the MEUF process such as pH, applied pressure, surfactant to metal ion ratio and nonionic to ionic surfactant molar ratio (α) were evaluated. Rejection of Ni and TW80 was 99% and 98% respectively whereas that for SDS was 65%. The flux and all resistances (fouling resistance, resistance due to concentration polarization) were measured and calculated for entire range of α respectively. A calculated flux was found to be declined with time, which was mainly attributed to concentration polarization rather than resistance from membrane fouling.

关键词： MEUF     Ni (II) ions     membrane resistance     concentration polarization     mixed surfactants    

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Optimization of microwave-assisted extraction for picroside I and picroside II from

Pravin WAKTE,Ajit PATIL,Bhusari SACHIN,Munnaza QUAZI,Shraddha JABDE,Devanand SHINDE

《化学科学与工程前沿（英文）》 2014年 第8卷 第4期   页码 445-453 doi: 10.1007/s11705-014-1458-2

摘要： The response surface methodology was employed to study the optimization of microwave-assisted extraction of picroside I and picroside II from Royle rhizomes. The effects of solid to solvent ratio, and extraction temperature, time and solvent on the yields of picroside I and picroside II have been investigated using Box-Behnken experimental design. The experimental data were fitted to second-order polynomial equations using multiple regression analysis and analyzed using the appropriate statistical method. By solving the regression equation and analyzing 3-D plots, the optimum extraction conditions were found to be: solid to solvent ratio, 10 : 90 (w/v); temperature, 60 °C; and extraction time, 60 s. Under the optimal conditions, the yields of picroside I and picroside II are 41.23 and 6.12 mg·g feed respectively, which are in good agreement with the predicted values. The ratio of solid to solvent significantly affects the yields of picroside I and picroside II. Application of microwave-assisted extraction of picroside I and picroside II from would dramatically reduce extraction time and solvent consumption.

关键词： Box-Behnken design     microwave-assisted extraction     picroside I     picroside II     Picrorrhiza kurroa    

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Microfluidic synthesis of renewable biosorbent with highly comprehensive adsorption performance for copper (II

Yong Zhu, Zhishan Bai, Bingjie Wang, Linlin Zhai, Wenqiang Luo

《化学科学与工程前沿（英文）》 2017年 第11卷 第2期   页码 238-251 doi: 10.1007/s11705-017-1627-1

摘要： A microsphere biosorbent with uniform size (CV= 1.52%), controllable morphology and component, and high mechanical strength was synthesized from chitosan by microfluidic technology combining with chemical crosslinking and solvent extraction. This chitosan microsphere (CS-MS) was prepared with a two-step solidification process, which was acquired by drying for the enhancement of mechanical property in final. The adsorption behavior of CS-MS towards copper (II) and main influencing factors on adsorption performance were investigated by batch experiments. Kinetic data highlighted dominant chemical bonding along with electrons transferring in adsorption process. Isothermal analysis indicated that adsorption capacity was relevant to the number of active site. All these explorations provided a new direction for preparing highly comprehensive performance sorbent used in heavy metal treatment via microfluidic technology.

关键词： chitosan microsphere     microfluidic technology     adsorption     copper (II)    

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Efficient removal of Cr(VI) and Pb(II) from aqueous solution by magnetic nitrogen-doped carbon

Wanyue Liu, Xiaoqin Liu, Jinming Chang, Feng Jiang, Shishi Pang, Hejun Gao, Yunwen Liao, Sheng Yu

《化学科学与工程前沿（英文）》 2021年 第15卷 第5期   页码 1185-1196 doi: 10.1007/s11705-020-2032-8

摘要： The magnetic nitrogen-doped carbon (MNC) was prepared from polypyrrole by a simple high temperature calcination process in this paper. The structure and properties of MNC were analyzed by scanning electron microscope, Fourier transform infrared spectroscopy, X-ray diffraction, Brunner Emmet Teller, vibrating sample magnetometer, and X-ray photoelectron spectroscopy. The capacity of MNC to adsorb Cr(VI) and Pb(II) was evaluated. The effects of the initial pH, dosage, concentration and temperature on the adsorption capacity of MNC were measured. MNC had a large specific surface area and a special porous structure. Its nitrogen and carbon sources were rich, and the ratio of carbon to nitrogen was fixed. The maximum Cr(VI)-adsorption capacity and maximum Pb(II) adsorption capacity of MNC could reach 456.63 and 507.13 mg∙g at 318 K, respectively. The pseudo-second-order model was used to describe the adsorption kinetics of MNC, and the Freundlich model was employed to discuss its isotherms. The adsorption process was affected by the electrostatic force, the reducing reaction, pores and chelation. The results of this study suggest that MNC is a material with superior performance, and is very easily regenerated, reused, and separated in the adsorption process.

关键词： magnetic     nitrogen-doped carbon     adsorption     Cr(VI)     Pb(II)    

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The performance of nitrate-reducing Fe(II) oxidation processes under variable initial Fe/N ratios: The

《环境科学与工程前沿（英文）》 2021年 第15卷 第4期 doi: 10.1007/s11783-020-1366-2

摘要：

•Bacterially-mediated coupled N and Fe processes examined in incubation experiments.

关键词： Denitrification     N2O emission     Fe(II) oxidation     Fe/N ratio     Fe minerals    

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Removal of Cu(II) and Fe(III) from aqueous solutions by dead sulfate reducing bacteria

Hong’en QUAN, He BAI, Yang HAN, Yong KANG, Jiao SUN

《化学科学与工程前沿（英文）》 2013年 第7卷 第2期   页码 177-184 doi: 10.1007/s11705-013-1324-7

摘要： The biosorption properties of dead sulfate reducing bacteria (SRB) for the removal of Cu(II) and Fe(III) from aqueous solutions was studied. The effects of the biosorbent concentration, the initial pH value and the temperature on the biosorption of Cu(II) and Fe(III) by the SRB were investigated. FTIR analysis verified that the hydroxyl, carbonyl and amine functional groups of the SRB biosorbent were involved in the biosorption process. For both Cu(II) and Fe(III), an increase in the SRB biosorbent concentration resulted in an increase in the removal percentage but a decrease in the amount of specific metal biosorption. The maximum specific metal biosorption was 93.25 mg?g at pH 4.5 for Cu(II) and 88.29 mg?g at pH 3.5 for Fe(III). The temperature did not have a significant effect on biosorption. In a binary metal system, the specific biosorption capacity for the target metal decreased when another metal ion was added. For both the single metal and binary metal systems, the biosorption of Cu(II) and Fe(III) onto a SRB biosorbent was better represented by a Langmuir model than by a Freundlich model.

关键词： sulfate reducing bacteria     biosorption     Cu(II)     Fe(III)    

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Urotensin II receptor antagonist reduces hepatic resistance and portal pressure through enhanced eNOS-dependent

Ruoxi Zhang, Jing Chen, Diangang Liu, Yu Wang

《医学前沿（英文）》 2019年 第13卷 第3期   页码 398-408 doi: 10.1007/s11684-019-0689-5

摘要： Increased serum urotensin II (UII) levels in human cirrhotic populations have been recently shown, but the long-term effects of UII receptor antagonist on the cirrhosis have not been investigated. To investigate the therapeutic effects of urotensin II receptor (UT) antagonist palosuran on rats with carbon tetrachloride (CCl )-induced cirrhosis, the hepatic and systemic hemodynamics, liver fibrosis, the metalloproteinase-13 (MMP-13)/ tissue inhibitor of metalloproteinase-1 (TIMP-1) ratio, hepatic Rho-kinase activity, and the endothelial nitric oxide synthase (eNOS) activity are measured in CCl -cirrhotic rats treated with palosuran or vehicle for 4 weeks. Primary hepatic stellate cells (HSCs) are used to investigate the changes in UII/UT expression and the effect of palosuran. Compared with the vehicle-treated cirrhotic rats, treatment with palosuran can reduce the portal pressure (PP), decrease the risk of liver fibrosis and the level of α smooth muscle actin, collagen-I (COL-I), and transforming growth factor β expression. However, treatment with palosuran can increase MMP-13/TIMP-1, p-vasodilator-stimulated phosphoprotein (p-VASP), and p-eNOS expression. Moreover, UII/UT mRNA expression increases during HSC activation. MMP-13/TIMP-1, COL-I, and p-VASP are inhibited after palosuran treatment. Our data indicate that long-term administration of palosuran can decrease PP in cirrhosis, which results from decreased hepatic fibrosis and enhanced eNOS-dependent HSC vasodilatation.

关键词： portal hypertension     cirrhosis     urotensin II     palosuran     hepatic stellate cell    

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标题 作者 时间 类型 操作

Experimental investigation of evolutive mode-I and mode-II fracture behavior of fiber-reinforced cemented

期刊论文

Effects of delamination in drilling glass/polyester composite

Mehdi GANJIANI, Majid SAFARABADI, Nabi MEHRI-KHANSARI, Hossein ORUJI

期刊论文

electrolysis cells with biocathodes and driven by microbial fuel cells for simultaneous enhanced Co(II) and Cu(II) removal

Jingya SHEN,Yuliang SUN,Liping HUANG,Jinhui YANG

期刊论文

anti-seismic engineering measures for intake tower based on non-dominated sorting genetic algorithm-II

期刊论文

A microextraction approach for rapid extraction and separation of Mn(II) and Co(II) using saponified

期刊论文

Co-present Pb(II) accelerates the oxidation of organic contaminants by permanganate: Role of Pb(III)

期刊论文

Approaching the binding between Cu(II) and aerobic granules by a modified titration and µ-XRF

Hongwei LUO,Longfei WANG,Zhonghua TONG,Hanqing YU,Guoping SHENG

期刊论文

Multi-objective optimization of a hybrid distributed energy system using NSGA-II algorithm

Hongbo REN, Yinlong LU, Qiong WU, Xiu YANG, Aolin ZHOU

期刊论文

Removal of Ni(II) ions from wastewater by micellar enhanced ultrafiltration using mixed surfactants

Amar D. Vibhandik, Kumudini V. Marathe

期刊论文

Optimization of microwave-assisted extraction for picroside I and picroside II from

Pravin WAKTE,Ajit PATIL,Bhusari SACHIN,Munnaza QUAZI,Shraddha JABDE,Devanand SHINDE

期刊论文

Microfluidic synthesis of renewable biosorbent with highly comprehensive adsorption performance for copper (II

Yong Zhu, Zhishan Bai, Bingjie Wang, Linlin Zhai, Wenqiang Luo

期刊论文

Efficient removal of Cr(VI) and Pb(II) from aqueous solution by magnetic nitrogen-doped carbon

Wanyue Liu, Xiaoqin Liu, Jinming Chang, Feng Jiang, Shishi Pang, Hejun Gao, Yunwen Liao, Sheng Yu

期刊论文

The performance of nitrate-reducing Fe(II) oxidation processes under variable initial Fe/N ratios: The

期刊论文

Removal of Cu(II) and Fe(III) from aqueous solutions by dead sulfate reducing bacteria

Hong’en QUAN, He BAI, Yang HAN, Yong KANG, Jiao SUN

期刊论文

Urotensin II receptor antagonist reduces hepatic resistance and portal pressure through enhanced eNOS-dependent

Ruoxi Zhang, Jing Chen, Diangang Liu, Yu Wang

期刊论文